Marek Orlik, Gerhard Gritzner,
"Chronocoulometric studies of the kinetics of the electroreduction of Eu3+ in"
, in Journal of Electroanalytical Chemistry, Vol. 582, Seite(n) 144 – 150, 2005, ISSN: 1873-2569
Original Titel:
Chronocoulometric studies of the kinetics of the electroreduction of Eu3+ in
Sprache des Titels:
Englisch
Original Kurzfassung:
Standard electrode reaction rate constants for the one-electron reduction of Eu(CF3SO3)3 on mercury in different concentrations of the supporting electrolyte tetrabutylammonium perchlorate in dimethylsulfoxide have been measured by single and double potential step chronocoulometry. Simulation programs were developed to extract the standard reaction rate constants from chronocoulometric experiments. The ks-values agreed well with data obtained from cyclic voltammetry and from ac techniques. The reaction rate constants depended on the concentration of the supporting electrolyte. Correlations of the ks-values with electrolyte properties are discussed.
Sprache der Kurzfassung:
Englisch
Journal:
Journal of Electroanalytical Chemistry
Volume:
582
Seitenreferenz:
144 – 150
Erscheinungsjahr:
2005
ISSN:
1873-2569
Anzahl der Seiten:
7
Notiz zur Publikation:
Chronocoulometric studies of the kinetics of the electroreduction of Eu3+ in
dimethylsulfoxide - Experiment and simulation
Marek Orlik and Gerhard Gritzner
J. Electroanal. Chem. 582 (2005) 144 – 150
Forschungs-