Gerhard Fuchs, Libuse Kisova, J. Komenda, Gerhard Gritzner,
"The influence of tetraethylammonium perchlorate on the electrode kinetics of Eu3+ in dimethylsulfoxide"
, in Journal of Electroanalytical Chemistry, Vol. 526, Nummer 1-2, Seite(n) 107-114, 5-2002, The influence of tetraethylammonium perchlorate on the electrode kinetics of Eu3+ in dimethylsulfoxide, Gerhard Fuchs, Libuse Kisova, Jaro Komenda, Gerhard Gritzner, J. Electroanal. Chem., 526 (2002) 107 - 114
Original Titel:
The influence of tetraethylammonium perchlorate on the electrode kinetics of Eu3+ in dimethylsulfoxide
Sprache des Titels:
Englisch
Original Kurzfassung:
The effect of different concentrations of the supporting electrolyte tetraethylammonium perchlorate on the standard electrode reaction rate constants for the one-electron reduction of Eu(CF3SO3)3 on mercury in dimethylsulfoxide has been measured. Two techniques, (i) ac polarography on the dropping mercury electrode and (ii) cyclic voltammetry in a two electrode system were employed. The ac data was evaluated both by the Randles and the by Sluyters methods. The standard reaction rates from cyclic voltammetry were extracted via a simulation program. Viscosities, resistivities, densities and the double layer capacitances of the electrolytes are given. Correlations between electrolyte properties and the -values are discussed. The standard electrode reaction rates were analyzed according to the Frumkin theory.
Sprache der Kurzfassung:
Englisch
Journal:
Journal of Electroanalytical Chemistry
Volume:
526
Number:
1-2
Seitenreferenz:
107-114
Erscheinungsmonat:
5
Erscheinungsjahr:
2002
Notiz zum Zitat:
The influence of tetraethylammonium perchlorate on the electrode kinetics of Eu3+ in dimethylsulfoxide, Gerhard Fuchs, Libuse Kisova, Jaro Komenda, Gerhard Gritzner, J. Electroanal. Chem., 526 (2002) 107 - 114
Forschungs-