Wolfgang Schöfberger,
"Stabilisation of tri-valent ions with a vacant coordination site at a corrole?metal interface"
, in Chemical Communications, Vol. 56, Royal Society of Chemistry, Seite(n) 11219-11222, 2021, ISSN: 1359-7345
Original Titel:
Stabilisation of tri-valent ions with a vacant coordination site at a corrole?metal interface
Sprache des Titels:
Deutsch
Original Kurzfassung:
By exploiting an established on-surface metallation strategy, we address the ability of the corrolic macrocycle to stabilise transition metal ions in high-valent (III) oxidation states in metal-supported molecular layers. This approach offers a route to engineer adsorbed metal complexes that cannot be easily fabricated by organic synthesis methods and bear a vacant axial coordination site for catalytic conversions.
Forschungs-